Scientists have spent years debating a strange property of gold: on the macro scale it is both physically and magnetically inert, but on the nano-scale, it is magnetic.
A new paper by Robson Fernandes de Farias of the Federal University of Rio Grande in Brazil hopes to shed light on this by examining the smallest possible gold cluster, particles of just two atoms. The explanation may trace its way back to Einstein’s theory of relativity.
For as long as humans have inhabited the earth, gold has been an object of desire. Gold flakes have been found in Palaeolithic caves dating back to 40,000 BCE, and it was prized by the pharaohs of ancient Egypt. Lust for it led the conquistadores to ravage the New World in the sixteenth century, while solutions of gold were consumed in the Middle Ages as a cure for syphilis.
In the modern world, gold is in our jewellery as well as in our electronics, and it is is increasingly finding its way back into medical practice in the form of nanoparticles used in tissue engineering. We might think that it holds few surprises, but it’s only in recent years that scientists have discovered its magnetism.
Gold (Au) in its bulk form, like the metal in a wedding ring, is not considered a magnetic material. Technically, it is classified as “diamagnetic”, meaning that it can be repelled by a magnetic field, but cannot form a permanent magnet.
Orignial Gold Magnet by KEENE. Seperate magnetic material from you concentrate. Makes panning easier and more efficient. Push the button down on top to grab magnetic material then release the button to let the magnetic material go. Also works well in a mini sluice to pull out iron on black rubber mat. The Gold Magnet has a yellow head in the shape of a magnet. It has two embroidered, light green eyebrows. Its eyes are black and embroidered on, and have white pupils in them. Below the pupils are dark green highlights, also embroidered on.
This is true on the macro scale, but as we know, when things get small their properties get weird.
In 2004, gold nanoparticles, tiny clusters of atoms a few nanometres in size, were shown to have paramagnetic properties, meaning they can attract other magnetic materials, just like miniature bar magnets.
Magnetism is caused by unpaired electrons surrounding the atoms of the material. Due to a quantum mechanical property called “spin”, unpaired electrons induce a magnetic dipole (like the two poles of a bar magnet). However, electrons often like to team up in pairs, and the opposing spin of the two electrons cancels out the magnetic effect.
A single atom of gold has an odd number of electrons, so it will always have one unpaired electron. But in bulk, these unpaired electrons can be shared between atoms, allowing them to find a buddy and form a pair. This means that metallic gold has no unpaired electrons, and it does not display classical magnetism.
Fernandes de Farias has tackled this problem by calculating the electronic structure of the smallest possible gold cluster, a two atom Au-Au dimer. His calculations show that in the Au-Au cluster, the two unpaired electrons held by the gold atoms do not form a pair, but are more stable on their own. He proposes that this effect becomes weaker as the cluster gets larger, meaning the bigger the particle, the weaker its magnetic properties.
Switch for mac download. Curiously, the properties of unpaired electrons in gold are largely explained by Einstein’s theory of relativity.
Gold is a large atom, so the unpaired electron orbiting furthest from the nucleus is moving very, very fast. Relativistic effects cause these electrons to be drawn closer to the nucleus, making them more stable than would be expected without the effects of relativity.
The stability of this unpaired electron is responsible for the very low reactivity of gold, explaining why it does not tarnish. It also affects the likelihood that this electron will pair with another electron in a nanoparticle. Thus, the magnetic properties of nanoscale gold are likely caused by the effects of relativity.
Related reading: How to produce gold without using cyanide
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- shawn johnson
winchester, ma, usa
Shawn -
Pure gold is not magnetic. That is, it doesn’t form a magnet on its own. If you put it in a magnetic field it will magnetize a tiny bit, but only so long as it’s in the field. and the direction of the magnetizaqtion makes it weakly repel the magnet.
There are alloys of gold, for example gold with more than about 20% of the atoms replaced by iron, which do magnetize on their own, at least when they are very cold, much colder than room temperature.
-Tamara (w Mike)
(published on 10/22/2007)
Follow-Up #1: magnetic silver?
- Anonymous
Mike W.
(published on 10/22/2007)
Follow-Up #2: Gold and magnets.. almost no attraction
- Lacy (age 24)
Winston-Salem, NC USA
Magnets strongly attract materials (like iron) which already themselves have magnetic domains. They do not significantly attract many metals like gold, aluminum, silver, and even some types of high-chromium stainless-steel, which lack such domains. In fact, pure gold is slightly repelled. A metal detector, if sensitive enough, should pick up the signal from a gold ring.
LeeH and Mike W.
(published on 10/22/2007)
Follow-Up #3: Magnetic test for gold?
- Anonymous
LeeH

Svn for mac free. (published on 11/07/2009)
Follow-Up #4: magnetic classification
- Jessica (age 12)
Singapore
Mike W.
(published on 09/05/2010)
Follow-Up #5: does a magnet stick to gold?
- ononomis (age 11)
fl.
Mike W.
(published on 07/24/2011)
Follow-Up #6: magnets picking up gold coins?
- Ted Sudol (age 62)
Ringwood

You're confused? How do you think we feel?
One thing that one might think- that the weak paramagnetism of simple models of metals could be involved- doesn't work because gold is slightly diamagnetic.
There seem to be several possibilities:
1. The coins have magnetic impurities.
2. The magnets are electromagnets and use some tricky spatial pattern of ac fields to use eddy currents to pull up the conducting coins. (Simple patterns would repel the coins.)
3. There's some sort of hoax.
Mike W.
(published on 03/31/2012)
Follow-Up #7: coins: loonies and toonies
- Richard E (age 28)
Calgary Albert canada
Mike W.
(published on 06/03/2012)
Follow-Up #8: magnets weakly repel gold
- deborah (age 50)
fla
We say repeatedly in this thread that magnets do not attract gold. In fact, they repel it very weakly.
Mike W. Railroad tycoon 3 for mac.
(published on 08/13/2013)
Follow-Up #9: Canadian coins: gold?
- Antonio (age 24)
zapopan
Those coins aren't really gold. See above.
An ac electromagnet will repel gold, because of the eddy currents.
Mike W.
(published on 09/11/2014)
Follow-Up #10: why so many repeat questions?
- Benedict (age 32)
Spain

Gold Magnets For Panning
I don't know.
Mike W.
(published on 04/12/2015)
Follow-Up #11: gold affecting magnets?
- Robert C Kahlert (age 48)
Leander
This does indeed sound implausible. Pure gold is very weakly diamagnetic, too weak to have any noticeable effect on an ordinary compass. Some iron impurities in the gold could make it weakly paramagnetic, but I doubt that could be strong enough to throw a compass off.
Mike W.
Gold Magnet Litter Robot
(published on 05/11/2018)
Follow-Up #12: magnetic panning for gold
- shawn johnson
winchester, ma, usa

Shawn- I guess the answer is just that the gold magnetizes so little even in a strong field that you can’t pick it up. You may not have much pure gold lying around, but you probably have some copper wire, which has similar magnetic and electrical properties. Your son can try picking it up with a magnet. No answer beats a nice experiment.
Mike W.
p.s. It turns out gold and copper are very weakly diamagnetic, which means they'll be slightly repelled by the magnet, unless they have magnetic impurities in them.
(published on 10/22/2007)
Follow-Up #13: Using magnets to pick up gold
- Andrew (age 21)
Bellevue Community College, WA
Gold Magnet Test
There is a version of this which may be more successful, though. If the magnetic field is both non-uniform and alternates in time, then the magnetic field will generate eddy currents in the electrically conductive gold flakes. These eddy currents will oppose the change in magnetic field, and the net effect will be to repel electrically conducting flakes from the alternating magnetic field. There may be other kinds of electrically conducting flakes in your sample, but gold is one of the better electrical conductors, and this level of separation may already be a big step forwards.Tom

(published on 10/22/2007)
Follow-up on this answer.
